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2025-10-04 09:04:41 UTC

John Carlos Baez on Nostr: Students who *memorize* organic chemistry consider it torture. But to *explore* is a ...

Students who *memorize* organic chemistry consider it torture. But to *explore* is a delight. It's like the difference between being force-fed and grazing at a buffet.

For example, yesterday I learned about 'crown ethers' - beautiful crown-shaped molecules of carbon, hydrogen and oxygen.

Here is a ball-and-stick model of one called 15-crown-5.

Why is it called that? I guess because it has 5 oxygens (in red) and 10 carbons (in black) for a total of 15 heavier atoms. Then there are a bunch of hydrogens poking out. It has perfect 5-fold symmetry.

One use of crown ethers is to hold metal ions. A sodium atom with one electron missing can snugly fit inside 15-crown-5. So can a transition metal with two electrons missing, like cobalt (Co²⁺), nickel (Ni²⁺), copper (Cu²⁺), or zinc (Zn²⁺) . Other metal ions fit better in other crown ethers. I'll show you how it works...

https://en.wikipedia.org/wiki/Crown_ether
https://en.wikipedia.org/wiki/15-Crown-5

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